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SUN CARE It should be strongly emphasised that


particle size result is variable based on the technique that is used for the analysis. The technique used in this analysis was to disperse the zinc oxide sample in water with a dispersing agent. The concentration of the dispersion is a function of the Bettersize 9300-S’s ability to detect the sample being analysed. Microscopic techniques, such as SEM


and TEM, can also be used to quantify the particle size. Although, again, a different set of numbers was obtained, the trend from smallest to largest particle size remains constant independent of the analytical technique used to determine it.


Conclusion Because the focus of this article is not on determination of particle size but sunscreen UV filters, it will be left that, independent of particle size analytical technique, the data concludes directionally there is a trend correlating the particle size of the zinc oxide powder with the final viscosity of the sunscreen. The primary use of this finding is that a formulator may be able to eliminate a thickening agent, an inactive ingredient, by using zinc oxide, a broad-spectrum UV filter. An experienced formulator will know how


to manipulate a sunscreen formulation to get the desired aesthetics. As the demand for more natural and environmentally safe products grows every year, the advantages of zinc oxide as a UV filter in sunscreens sets it apart. It is classified by the FDA as GRASE. As long as it is


TABLE 4: NATURALLY DERIVED SPF 15 ZINC OXIDE-BASED SUNSCREEN FORMULATION


Sequence 1


1


1 1


2 3 3 3 4


Ingredient Plant based emollient


70% Naturally derived emollient


Emulsifier, 98% naturally derived


Natural dispersing agent Zinc oxide


Solvent (deionized water) Preservative


Emulsion stabilizer pH adjuster


%


20 15


15 1


10


37.5 1


0.5 as needed


not nanoparticle zinc oxide, it is also recognised as being reef-safe and therefore environmentally the right choice for a UV filter. As shown in this article, a formulator has the


ability to modify the finished viscosity of the sunscreen without changing the SPF value by selecting zinc oxides with varying particle sizes and potentially eliminating the need for viscosity modifiers.


109


2. Sun Care Regulations Round-up! SpecialChem. 2020. Available from: https:// cosmetics.specialchem.com/tech-library/ article/sun-care-regulations-roundup


3. Sunscreen: How to Help Protect Your Skin from the Sun [Internet]. US Food & Drug Administration. 2019. Available from: https:// www.fda.gov/drugs/understanding-over- counter-medicines/sunscreen-how-help- protect-your-skin-sun


4. Boerner L.K What’s in sunscreen, and how does it protect your skin from the sun’s rays? Chemical & Engineering News. 2021 Jul 21, 99(27)


5. EWG. The trouble with ingredients in sunscreens [Internet]. Available from: https:// www.ewg.org/sunscreen/report/the-trouble- with-sunscreen-chemicals/


6. Nohynek G.J, Dufour E.K Nano-sized cosmetic formulations or solid nanoparticles in sunscreens: A risk to human health? 2012 Jul;86(7):1063-75. doi: 10.1007/s00204-012- 0831-5. Epub 2012 Mar 31. PMID: 22466067. Arch Toxicol. 2012 Jul;86(7):1063–75


PC


References 1. Grum T. Sunscreen regulations across the globe: What industry needs to know. 2019. Available from: https://www.cosmeticsdesign- europe.com/Article/2019/08/19/Sunscreen- regulations-in-the-world-from-European- Union-USA-Canada-to-China#


7. Sabzevari N. Sunscreens: UV filters to protect us: Part 1: Changing regulations & choices for optimal sun protection. International Journal of Women’s Dermatology. 2021, 7:28–44


8. Sunscreen drug products for over-the-counter human use. Federal Register. 2019 26 Feb, 84(38):6204–75


9. Protect Land + Sea Certification. Haereticus Environmental Laboratory. 2018. Available from: http://haereticus-lab.org/protect-land- sea-certification-3/


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April 2022 PERSONAL CARE


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