SUN CARE 85
experience that protects skin from the sun’s harmful rays.
In addition to its many end-user benefits, the ingredient also boasts a number of advantages for formulators. As a water-based film-former, it allows for greater formulation and manufacturing process flexibility because of its ability to achieve optimal performance in pure film, water-in-oil and oil-in-water formulations. The polymer is also readily compatible with
common cosmetic ingredients, which means formulators can bring the sensory benefits that consumers desire into their sun care, skin care and even cosmetic products like alphabet creams.
Sun care with sophistication With more refined views of skin care being cultivated across the growing Asian market, consumers expect sun care products with both aesthetics and high SPF performance.
Table 2: Sunscreen Formulation A with 6% octylmethoxycinnamate and 1% oxybenzone. Phase Ingredients A
Water, DI
ACULYN 33 Polymer Glycerin
Tetrasodium EDTA B
SUNSPHERES powder Octyl methoxycinnamate Oxybenzone
C12-15 alkyl lactate
PVP/eicosene copolymer Cyclomethicone Stearic acid
C Triethanolamine, 99%
Control % w/w 80.72
3.33 1
0.1 0 6 1 2
1.5 2
1.5 0.85
3.33 1
0.1
5.55 6 1 2
1.5 2
1.5 0.85
Table 3: Sunscreen Formulation B with 7.5% Octylmethoxycinnamate, 2% Oxybenzone and 3% Octyl Salicylate.
Phase Ingredients A
Water, DI
PVM/MA decadiene crosspolymer Butyl glycol
B
SUNSPHERES powder PEG-20 Stearate
Glyceryl stearate & laureth-23 Octyldodecyl neopentanoate Octyl palmitate Glyceryl dilaurate
Octyl methoxycinnamate Oxybenzone Octyl salicylate
C Sodium hydroxide 10%
Glyceryl polymethacrylate & propylene glycol
Glyceryl polymethacrylate & propylene glycol & PVM/MA copolymer
D
Diazolidinyl urea & iodopropynyl butylcarbamate Methylparaben
November 2019
Control % w/w 71.7 0.5 3 0
1.5 2 1 2
0.5 7.5 2 3
1.3 3 0.5
0.3 0.2
Test % w/w 66.15 0.5 3
5.55 1.5 2 1 2
0.5 7.5 2 3
1.3 3 0.5
0.3 0.2
A one-two UV protection punch The SPF-enhancing capabilities of this ingredient can be augmented through an oil-in-water emulsion with another prominent Dow ingredient for sun care: SunSpheres™ PGL. This styrene/acrylates copolymer can be combined with the aforementioned SPF booster to more than double the SPF of a given formulation while keeping viscosity within the range of aesthetic approval. Notably, that increase in SPF is achieved synergistically across various surface-treated inorganic filters.
General procedures: l Mix all Phase A ingredients and heat the mixture to 75ºC
l Mix Phase B and heat mixture to 75ºC l Add Phase B to Phase A l Cool to 40ºC and add Phase C (Soltex™ INO Polymer)
l Add Phase D (preservative) l Homogenise for 10 minutes SunSpheres PGL is supplied as a 25.5
percent solids emulsion, but Dow also provides the same UV protection- enhancing properties in the form of a white, non-dusty, flowable powder. Both forms of the additive comprise hollow styrene/acrylic copolymer spheres measuring approximately 350 nm in diameter. Similar to the PGL version of the copolymer, the powdered form enables a generous SPF boost without negative impact on viscosity.
PERSONAL CARE ASIA PACIFIC
Test % w/w 75.17
Since whitening and anti-ageing products need continually higher SPF levels to counteract the harsh effects of the sun and environmental pollutants, formulators often face difficulty in creating products that do not run or leave white traces. Enter Dow’s Soltex™ INO Polymer, an ingredient that improves product aesthetics of formulations containing inorganic UV filters without compromising SPF performance. Soltex INO Polymer enhances the SPF
performance of various cosmetics by improving the overall dispersion of inorganic particles, such as TiO2
and ZnO, in
sunscreen formulations. This ultimately leads to an improved SPF, product aesthetics and overall sensory experience. Sunscreens that contain inorganic UV actives, such as TiO2
, offer protection by
absorbing and scattering UV light. Particle aggregation can reduce UV attenuation — along with the SPF — of the sunscreen. This proprietary acrylate and
methacryloyloxyethyl phosphate copolymer works by attaching to the TiO2
surface,
which provides more steric hindrance among TiO2
dispersion of TiO2
particles. The enhanced and ZnO makes it
possible to use less of these additives in sun care formulations, achieving the same UV attenuation effect while improving product appearance, aesthetics and user experience.
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