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TECHNOLOGY LEDs


Going Green with cubic GaN


Conventional green LEDs are plagued by strong internal electric fields, which impair recombination and make it difficult to address droop. The solution is switch to growth on the cubic phase of GaN, which is free from internal fields and has a smaller bandgap, making it easier to reach longer wavelengths.


By MARK DURNIAK and CHRISTIAN WETZEL from RENSSELAER POLYTECHNIC INSTITUTE


THE SOLID-STATE LIGHTING REVOLUTION is now upon us. Businesses and homeowners are trimming their electricity bills, and by 2030 an ever-increasing uptake of LED bulbs could lead to savings as high as $30 billion, according to the US Department of Energy.


Most consumers that are currently investing in solid-state lighting are buying bulbs that employ a highly efficient blue LED to excite a phosphor, which then re-emits photons of lower energy, usually in the yellow spectral region. Colour mixing of blue and yellow creates a white-emitting luminaire.


Figure 2. Model of the cubic/hexagonal GaN interface


This approach has the merit of simplicity, but it is not ideal. One weakness is the inherent conversion efficiency ceiling, stemming from the Stokes loss in the down-conversion of high-energy blue photons to lower energy yellow photons. In addition, the colour temperature or ‘warmness’ of the white light


is fixed, governed by the mix of phosphors.


These limitations can be lifted with luminaires based on the colour mixing of several LEDs, such as those emitting in the red, green and blue. With this approach, which can involve three or more LEDs, it is possible to construct a high-quality, colour-tuneable light source. The Philips HUE bulb is an example of this, which allows users to pick the colour they want by running an app on their smart phone.


Figure 1. Growth of hexagonal GaN in ‘V-shaped’ trenches leads to the formation of cubic GaN


54 www.compoundsemiconductor.net January / February 2014


Another advantage of the colour mixing approach is that it can achieve higher theoretical efficiencies than phosphor conversion. The efficacy of this form of lighting is then governed by the efficiencies of the LEDs.


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