HAIR CARE CH3 CH2
CH N
CH2 O
C C
(CH3)3 +
CH3 X
NH N
CH3 CH3 CI – Y
Figure 4: Chemical structure of the quaternised polymers selected for this study. Polyquaternium-28
improved colour protection of shampoo formulations while maintaining other important product attributes such as foaming, rinsability and minimised build-up of conditioning additives on hair. This article was first presented at the 26th IFSCC Congress in Paris, 2014.
References 1
Brown K. Hair coloring. In: Johnson DH ed. Hair and hair care. New York: Marcel Dekker, 1997: 198-204.
2 Medice ALA, Joekes I. Colour fading in permanent hair dyed. 22nd IFSCC Conference, Brazil, 2013.
3
Fernández S, Colom O, Fariñas S, Vallecillos R, Bermúdez M, Casadó F. Fading of permanent dyed hair depending on the chemical and physical pretreatment. 25th IFSCC Congress, Barcelona, 2008
7 4 5 PC n Polyquaternium-55
Rigoletto R, Zhou Y. Polyelectrolyte complex for mending damaged hair. Cosmetics & Toiletries 2009; 124 (3): 76-87
Kiplinger J, Bendejacq D, Leroy E, Adamy M. A study on the influence of surfactants on hair color fading. Annual Scientific Meeting and Technology Showcase of the Society of Cosmetic Chemists (SCC), 2009.
6
Jaynes BS, Jennings J, Andrianov C. An evaluation of cationic polymers for the prevention of fading in oxidative hair dyes. 24th IFSCC Congress, Osaka, 2006.
Schlosser A. Silicones used in permanent and semi-permanent hair dyes to reduce the fading and color change process of dyed hair occurred by wash-out or UV radiation. J Cosmet Sci 2004; 55 (Suppl): S123-31. Proceedings of the First Conference on Applied Hair Science. June 9-10, 2004. Princeton, New Jersey, USA.
J Cosmet Sci 2004; 55 (Suppl v): S1-214.
8 Gamez-Garcia M. Examination of cationic polymer deposition onto hair from an emulsified silicone oil-containing shampoo through dual fluorescent technologies. 21st IFSCC Congress, Buenos Aires, 2010.
9
Zhou Y, Foltris L, Moore DJ, Rigoletto R. Protection of oxidative color fading from shampoo washing by hydrophobically modified cationic polymers. J Cosmet Sci 2008; 60 (2): 217-38.
10 Gruber JV. Synthetic polymers in cosmetics. In: Goddard ED, Gruber JV eds. Principles of polymer science and technology in cosmetics and personal care. New York: Marcel Dekker, 1999: 217-74.
11 Zhou Y, Foltris L, Rigoletto R, Moore DJ. Protection of oxidative colour fading from fading or washing out. US Patent Application 61/018,055.
m CH2 O
Quaternised groups
CH3
CH N
CH2 O CH3
C C
(CH2)3
NH N
CH3 CH3 CH2 O CH3
C C
NH CH2
CH2 CH2
N CI C12H25
+ – CH3 p
Hydrophobic groups
Quaternised groups
O
September 2015 PERSONAL CARE 49
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