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tions among the shell components and phase transfor- mation within the a morphous silica take place at high temperature, the amount and rate of these reactions will significantly affect the specific heat capacity values used in modeling. In the inverse method, the shell is heated rapidly when metal is poured and cooled down at a relatively slower cooling rate as the metal solidifies. Tese processes associate with more instantaneous measure- ment of a property which includes latent heat effects from phase changes. However, a small mass specimen is equilibrated at an environmental test temperature in the laser flash. Consequently, the transformation occurring in the inverse method may have already taken place prior to the measurement by the laser flash method. Similarly, when comparing the total enthalpy change


from room temperature (68F [20C]) to 2,885F (1,420C) among the values from theoretical calculation of the inverse method and the laser flash method, the laser flash method shows similar values, because the thin speci- men used in the laser flash method was under partially thermally stabilized condition which is closer to thermal equilibrium. Te shell in reality is hardly in thermal equilibrium conditions, thus the inverse method provided more realistic effective heat capacity values for modeling the pouring and solidification processes. Termal property data measured by laser flash could be used as the starting point in the automatic optimi- zation process, which greatly reduces the number of simulation cases needed to approach a well fitted case and reduces the potential extrapolation error in itera- tion step estimates. Te theoretical thermal conductivity of pure silica with 33% porosity was plotted in Fig. 5 as well as ther- mal conductivity values of shell #1 and shell #3. Tose industrial shells had similar measured and theoretical values of thermal conductivity at a lower temperature but were more heat conductive at a higher temperature. Tis could result from different particle and porosity size distributions, since smaller particle size with higher grain boundary to volume ratio will lower thermal conductiv- ity. Tis theoretical model may not consider the photon conductivity of the pore phase at higher temperature. Obtaining the data from laser flash and then applying the data in the inverse method can be time consuming and costly. Te researchers recommend that industries developing their own investment casting shells pick the thermal property data of shells from given investment casting facilities in the study with the closest composition and utilize those estimates in their simulations. Whoever uses the data must measure the bulk density and poros- ity of their shells, because bulk density is used in most simulations and porosity is needed to adjust the value of thermal conductivity. ■


Tis article was based on the paper, “Termal Property Database for Investment Casting Shells,” (Paper No. 14-020, presented at the 118th Metalcasting Congress.


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。ѫם造铸ه ,Շ੮й


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