CHAPTER 2 UNDERSTANDING UTILITY NATURAL GAS
and the source is located within the flammable limits, an explosion can occur. One of the most difficult tasks for a responder to accomplish at an emergency scene is to eliminate all sources of ignition. Only specially designed facilities can completely eliminate ignition sources with intrinsically safe designed lights, motors and switches. A more practical street approach is not to focus solely on ignition sources. Rather responders should monitor for the flam- mable range and remain well back from the danger zone or 10% of the LEL. If neither of these actions can be done effectively, responders should evacuate and wait for the local distribution company to arrive.
Health Hazards
Natural gas is a nontoxic fuel. However, under the right conditions, it can be a health hazard. It can be an asphyxiation hazard and the odorant can be un- healthy if breathed in for a long time. Improper installation of the gas-fed units can also create dangerous situations.
Toxic By-products of Combustion
Complete combustion of natural gas produces water vapor and carbon diox- ide. However, incomplete combustion, indicated by a yellow rather than blue flame can create harmful by-products such as carbon monoxide (CO), a lethal,
CARBONMONOXIDE CO
740,000 ppm 1,000,000
10-15 Mins.
dizziness & Headache 5-10 Mins.
Cherry red skin violent headache
Headache 1-2 hr.
Headache 2-3 hr.
tlV-tWa Pel
(OsHa) 25 ppm 400 ppm 200 ppm FIGURE 2.9 Concentration levels and physiological effects of carbon monoxide. 32 1,000 ppm 1,200 ppm tlV-C
reddish skin
stel IDLH 3,200 ppm 2,000 ppm 1,300 ppm 400 ppm
10% of LEL
irreversible damage 1 Hour
death or 6,400 ppm
10,000 ppm 1%
Unconsciousness & death 1-3 Mins.
1.2%
12.8% LEL
74% LEL
irreversible damage
death or
12,800 ppm
128000 lel
ppm 100%
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