52 Portable / Field Testing Stack Gas VOC Monitoring
There are various definitions of VOCs. One of the most adopted definition, defines a VOC as any organic compound which is emitted from non-natural processes and has a photochemical ozone creation potential.
A variety of primary and secondary legislation has been introduced to impose limits on industrial VOC emissions. In Europe two regulations are well established: 1. EN 12619 FID method for low concentrations of TOC. It is a standard reference method (SRM) for monitoring TOC from incinerators. It has been validated as suitable for measuring low level gaseous or vapour phase TOC emissions over a range of 0 - 20 mg/m3
TOC found in emissions from processes which use solvents. The standard has been validated as suitable for measuring emissions up to 500 mg/m3
. 2. EN 13526 - FID method for high concentrations of TOC. it has a standard for higher concentrations of .
VOCs are emitted by wide range of different industries. For example, emissions can arise through the evaporation of organic compounds used as solvents; through incomplete combustion of fuels; and through biological degradation of organic matter as in fermentation processes.
Emissions also occur over a wide range of concentrations and emission limits are sector specific. For instance, stack emissions of solvents from coating processes can range between less than 20 mg/m3
up to several thousand g/m3 .
If the stack gas is relatively hot and wet, there is a high probability of condensation when the gas sample touches a cold surface. A FID for stack monitoring should, therefore, be well done in order to prevent condensation of either moisture or VOCs in the sample line (i.e. be equipped with a heated-line and heated detector).
Many simple, unheated, portable FIDs have been designed for applications in health and safety screening and fugitive emissions monitoring. These simple FIDs also usually have a wider spectrum of response factors, so their accuracy and precision will never be as great as the highly engineered, complex, heated FIDs.
Pollution (Italy) Polaris FID is designed to be compliant with EN 12619:1999, EN 13526:2002 and US EPA Method 25A. These regulations impose that the temperature of the coolest point shall be at least 20°C above the flue gas temperature. Since the chimney’s fumes are very hot and they are above the ambient temperature, then the temperature of the sampling line and internal parts of Polaris FID are heated up to 180°C to prevent condensation and reduce adsorption losses.
Polaris FID is a truly portable instrument and completely mounted analyser because in only 13 kilograms it incorporates inside all that is needed for the analysis: batteries, hydrogen storage accumulator,
activated charcoal filter for the combustion air, span gas cylinder for the calibration and technical air cylinder for zeroing signal at every measurement. In addition, there is an input for external gas cylinders (H2, span gas, zero air) when continuous long time monitoring is required. The external optional docking station allows also methane/non-methane output configurations. The integrated CPU automatically control several extra functions: flame injection, the menu-driven handling as well as a full auto testing for any failure.
Another advantage of Polaris FID is described by the hydrogen cartridge. It doesn’t contain hydrogen at high pressure. Here the hydrogen is chemically bonded with a special metal alloy and it is slowly released assuring about 30 working hours.
Even when the oxygen levels are unpredictable, Polaris FID well handles and minimises the effects of oxygen synergism. If you know how it’s hard to work upon the chimney, you can appreciate compact and lightweight instruments.
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26237pr@reply-direct.com New Barometric Pressure Sensor
The latest innovation from Felix Technology (Canada) is a Barometric Pressure Sensor FT5006 that combines high accuracy and low power over a wide range of pressures and temperatures.
The model FT5006.10 provides a calibrated 0-5 VDC analogue output. Analogue current consumption is less than 3mA. A special “sleep” mode further reduces current to about 1 µA. RS232 serial output is also available in the standard sensor.
The model FT5006-20 features a standard 4-20 mA analogue output. Two serial options, RS-232 and RS-485, are included in this model. The compact size of the barometer allows easy mounting in almost any standard instrument enclosure.
A plug-in connector simplifies wiring. The weatherproof enclosure offers a convenient mounting location while the pressure port helps minimise dynamic pressure errors due to severe wind.
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Mobile Gas Analysis for Pressure Lines
With their new "Oxybaby P", Witt-Gasetechnik (Germany) have introduced a hand held portable
analyser that determines the O2/CO2 gas levels in a pressurised supply line.
As many portable devices for gas analysis can only be used for low-pressurised test objects such as modified atmosphere packaging the gas pressure in supply lines is much too high for the sensitive measuring cells of the analyser. By integrating an ultra-compact pressure regulator in the newest version of its proven hand-held analyser, "Oxybaby", Witt now allows inlet pressures of up to 10 bar. Depending on the requirements, the Oxybaby determines the concentration of oxygen and/or carbon dioxide in a range of 0 – 100 %, and displays the results in increments of 0.1 %.
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This opens up entirely new possibilities for quality controllers: The new version of "Oxybaby P" allows the composition of a gas mixture to be monitored at any location in the gas line as well as directly at the point of consumption. This will insure the accuracy of the gases before the gas consumer has been connected whether the line contains the required gas or whether the mixture has the correct concentration. The handling is very simple: The hand-held device and the extraction point are simply connected by a small hose. The version for the conventional G1/4" male thread with collar nut is included in the scope of delivery. Other versions are optionally available.
In addition to the system advantage, the benefits of the device include the easy, single-hand operation, the small size of the shock-resistant housing (approximately 18 cm), the long-lasting and fast- charging battery, the low weight (approximately 600 g) and the illuminated LCD display with intuitive user interface in several languages. Even at the maximum measuring range, the measurement itself takes at most ten seconds, must faster than Thermal Conductivity gas analysers. The integrated circulating memory on the 6.0 models captures the results for 500 measurements. Data transfer to a PC for further processing is possible via a USB connection. Upgrades such as a bar code reader and Bluetooth are planned.
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