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Lithium batteries don’t commit suicide. They’re murdered.


By Marcus Jones, DipMarSur(IND), AMIMAREST


LiBs batteries are increasingly used in the marine industry. Their advantages are many: compact and cheap, with higher energy density, they can help to cut down sharply on fossil fuel use. Problems are rare, but when things go wrong the results have a high impact and take up emergency resources for a considerable time.


What is a lithium battery


A LiB is what is sometimes referred to as a rocking chair battery and was invented in the 1970s. Types are named by their Cathode material chemistry, LFP (Lithium Iron Phosphate), and NMC are the most common. The current collectors are metal foils (Cu) Copper for the Anode and, (Al) Aluminium for the Cathode. Spread with a thin paste layer of Carbon nano particles on the (Cu) Anode and the Lithium chemical compound paste on the (Al) Cathode. Between them is a layer of organic solvent with a microns-thick Polyethylene Ion porous separator in the middle. This completed sandwich is then, rolled or folded into form factor called a cell and packed into casing.


Lithium cells come in three types or form factors:


A. B.


The cylindrical cell, such as the lithium 18/6/50. This is shaped like an AA battery and can be used alone or linked in series. It is usually used for smaller devices such as power tools but can be linked up to power larger things like Tesla cars.


The soft flexible Pouch cell often the size of an A4 sheet of paper but can be smaller: it can be shaped to fit within a housing and was originally developed for Electric Vehicles (EVs).


C.


The Prismatic cell with a plastic case. This is about the shape and size of a 6 cigarette pack stacked in pairs side by side. Victron LPF marine batteries use this cell type. LFP cells produce higher volumes of hydrogen gases and take longer to ignite the vapour cloud increasing the risk of VCE.


The cells are made into strings connected in series and then made into modules connected in parallel which form the battery pack. This is packaged into a metal or plastic enclosure suitable for the intended use.


74 | ISSUE 111 | MAR 2025 | THE REPORT


Image credit: Mitch Jacoby / C&EN


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