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76 Chapter 4 • Heat


Heat lost = Heat gained mc3t = mc3t


m× 494 × (850 – 25) = 30 × 4 200 × (25 – 19,5) 494m × 825 = 126 000 × 5,5 407 550m = 693 000


\ m = 693 000 = 1,7 kg


4.9 Thermal expansion


Te volume of most substances increases when their temperature is increased. In engineering, the increase in volume of a liquid or gas is of most importance. In the case of solids, the increase in area and length is of most importance. When a substance is cooled, the reverse takes place.


An exception to this rule is water. It shrinks as it is cooled until it reaches a temperature of about 4 °C. At this point, it starts expanding (this accounts for the bursting of bottles in a deep freeze and the bursting of water pipes) until at 0 °C it reverts back to the rule (but only aſter all the water has been converted to ice) and starts shrinking once again.


The increase in volume during this 4 °C temperature change is in the region of 9%.


The ratio by which a given amount of substance expands per °C rise in temperature, is known as its coefficient of expansion. Each material has three coefficients of expansion namely, volume, area and length.


4.9.1 Volumetric expansion Experiment 4.3 Volumetric expansion


For this experiment, ametal ball and ring, fig. 4.7, is used. At normal roomtemperature the ball is slightly smaller than the ring and it slips through easily. When the ball is heated, it expands in volume. Tis is obvious as the heated ball rests on the ring. If leſt like this it will soon be seen that when the ball has cooled down, it will fall through the ring.


Metal ball Ring


407 550


Fig. 4.7 Ball and ring


g. 4.7 Ball and ring


Uses: Liquid in glass thermometers and thermostats in motor cars are common examples of volumetric expansion.


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