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Based on the DPPH radical scavenging activity test results, Irganox L06 and BHT demonstrated the highest potential as antioxidants.


The heat test results highlighted Irganox L101, Irganox L109, and Irganox L06 as the most effective antioxidants. The results from the oxygen and heat tests further supported these findings, particularly endorsing the use of Irganox L101 and Irganox L06.


In summary, taking into account both the DPPH% and the stress test outcomes, Irganox L06 and Irganox L101 emerge as the most suitable antioxidant additives for white oils, with Irganox L06 being a phenolic antioxidant and Irganox L101 an aminic one.


The effect of antioxidant concentration (ranging from 0.1% to 0.8%) on ΔTAN and V/V0 values was found to be statistically insignificant for these antioxidants.. Consequently, the lowest concentration tested (0.1%) is recommended for use in white oils to minimise the cost of additives.


For situations that demand higher antioxidant capacity, the highest concentration tested (0.8%) of Irganox L101 is recommended, as DPPH% showed a linear increase with concentration up to this point. In the case of Irganox L06, a concentration of 0.3% is recommended, as the antioxidant activity plateaus beyond this level.


References [1] Hamblin P (1999) Oxidative stabilisation of synthetic fluids and vegetable oils. Journal of Synthetic Lubrication 16 (2):157-181. doi:https:// doi.org/10.1002/jsl.3000160206


[2] Rabelo Neto RC, Lima DO, Pinheiro TDS, Almeida RF, Castro Dantas TN, Dantas MSG, Araújo MAS, Cavalcante CL, Azevedo DCS (2004) Thermo-Oxidative Stability of Mineral Naphthenic Insulating Oils: Combined Effect of Antioxidants and Metal Passivator. Industrial & Engineering Chemistry Research 43 (23):7428-7434. doi:10.1021/ie049645o


[3] Duong S, Lamharess-Chlaft N, Sicard M, Raepsaet B, Galvez ME, Da Costa P (2018) New Approach for Understanding the Oxidation Stability of Neopolyol Ester Lubricants Using a Small-Scale Oxidation Test Method. ACS Omega 3 (9):10449- 10459. doi:10.1021/acsomega.8b00370


LUBE MAGAZINE NO.184 DECEMBER 2024 17


[4] Somayaji A, Aswath PB (2009) The Role of Antioxidants on the Oxidation Stability of Oils with F-ZDDP and ZDDP, and Chemical Structure of Tribofilms Using XANES. Tribology Transactions 52 (4):511-525. doi:10.1080/10402000902745499


[5] Chao M, Li W, Wang X (2015) Thermal decomposition kinetics and anti-oxidation performance of commercial antioxidants. Journal of Thermal Analysis and Calorimetry 120 (3):1921-1928. doi:10.1007/s10973-015-4525-0


[6] Yao J (1997) Evaluation of sodium acetylacetonate as a synergist for arylamine antioxidants in synthetic lubricants. Tribology International 30 (11):795-799. doi:https://doi. org/10.1016/S0301-679X(97)00046-7


[7] Alexsandra de Sousa Rios M, Sales FAM, Mazzetto SE (2009) Study of Antioxidant Properties of 5-n-Pentadecyl-2-tert-amylphenol. Energy & Fuels 23 (5):2517-2522. doi:10.1021/ ef800994j


[8] Kamal RS, Ahmed NS, Nasser AM (2013) Study the efficiency of some compounds as lubricating oil additives. Applied Petrochemical Research 3 (1):1-8. doi:10.1007/s13203-012-0020-8


[9] Al-Sammerrai DA, Barbooti MM (1985) Evaluation of aromatic extracts as antioxidants for mineral oils. Industrial & Engineering Chemistry Product Research and Development 24 (1):171- 175. doi:10.1021/i300017a032


[10] Lee J, Chung H, Chang P-S, Lee J (2007) Development of a method predicting the oxidative stability of edible oils using 2,2-diphenyl-1-picrylhydrazyl (DPPH). Food Chemistry 103 (2):662-669. doi:https://doi. org/10.1016/j.foodchem.2006.07.052


[11] Gatto VJ, Elnagar HY, Moehle WE, Schneller ER (2007) Redesigning alkylated diphenylamine antioxidants for modern lubricants. Lubrication Science 19 (1):25-40. doi:https://doi.org/10.1002/ ls.28


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