Food, Flavor, and Fragrance Applications Perfume


Column: HP-INNOWax 19091N-133 30 m x 0.25 mm, 0.25 µm


Carrier: Helium, 30 cm/sec 0.9 mL/min constant flow


Oven: 80°C for 1 min 80-250°C at 5°C/min 250°C for 2 min


Injection: Split, 250°C Split ratio 20:1


Detector: MSD, 280°C 1


Suggested Supplies Septum: Advanced Green, 5183-4759 Liner: Split, single taper, low pressure drop, glass wool, 5183-4647 Seal: Gold plated seal, 18740-20885 Syringe: 5 µL tapered, FN 23-26s/42/HP, 5181-1273


1. Limonene 2. Linalool 3. Linalyl acetate 4. Benzyl acetate 5. Citronellol 6. Benzene ethanol


7. a-Methyl Ionone 8. Carvocrol and geraiol 9. Isoamyl salicylate 10. n-Amyl salicylate


11. Commamyl acetate 12. Acetylcedrene 13. Diethyl phthalate 14. Tonalid 15. Coumarin 16. Musk xylene 17. Benzyl benzoate 18. Benzyl salicylate 19. Musk ketone


3 2 5 7 11 13 18 6 8 4 9 15 12 14 19 16 17 10


0


5


10


15


20 Time (min)


25


30 GCFF006


Chiral Compounds in Essential Oils and Fragrances


Column: HP Chiral ß 19091G-B233 30 m x 0.25 mm, 0.25 µm


Carrier: Hydrogen, 39 cm/sec, Constant pressure Oven: 65°C for 1 min 65-170°C at 5°C/min


Injection: Split, 250°C Split ratio 30:1


Detector: FID, 300°C Sample: 1 µL 0.25 ng/µL each analyte in Hexane


5 1 2 56 7 8 14


9 10 13 11


3 4 12


1. 1,2-Dimethylbenzene 2. Myrcene 3. (-)-Camphene 4. (+)-Camphene


5. (+)-b-Pinene 6. 1S-(-)-b-Pinene 7. Cineole


8. (+)-Citronellal 9. 1S,2R,5S-(+)-Menthol 10. 1R,2S,5R-(-)-Menthol


11. a-Terpineol 12. (+/-)-Isoborneol 13. (+)-Borneol 14. trans-Cinnamaldehyde


10 Time (min) 15 20 GCFF008


Menthol


Column: Cyclodex-ß 112-2532 30 m x 0.25 mm, 0.25 µm


Carrier: Hydrogen, 55 cm/sec Oven: 105°C isothermal Injection: Split, 250°C Split ratio 1:100


2 1 3 4


Detector: FID, 300°C Nitrogen makeup gas at 30 mL/min


Sample: 1 µL of 1 µg/µL each chloroform 13 min GCFF009


1. (+)-Neomenthol 2. (-)- Neomenthol 3. (+)-Menthol 4. (-)-Menthol


Order online at www.agilent.com/chem/store


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