Fragrance Reference Standard II


Column: DB-WAX 122-7032 30 m x 0.25 mm, 0.25 µm


Carrier: Helium at 25 cm/sec, measured at 150°C


Oven: 45°C for 2 min 45-250°C at 3°/min 250°C for 34 min


Injection: Split, 250°C Split ratio 1:50


Detector: MSD, 250°C transfer line Sample: 1 µL of a 1:20 dilution of neat sample in acetone


Suggested Supplies


Septum: Advanced Green, 5183-4759 Liner: Split, single taper, low pressure drop, glass wool, 5183-4647


Seal: Gold plated seal, 18740-20885 Syringe: 5 µL tapered, FN 23-26s/42/HP, 5181-1273


4. 2,3-Butanedione (diacetyl) 5. Methyl butyrate 6. 7. 8.


1. Acetone 2. 3.


Ethyl propionate Ethyl acetate


9. 2,3-Pentanedione (acetyl propionyl) 10. Camphene 11. Ethyl isovalerate


Ethyl butyrate


12. b-Pinene 13. Ethyl pentanoate 14. Myrcene 15. Allyl butyrate 16. Limonene 17. 1,8-Cineol 18. 3,5,5-Trimethylhexanol 19. 3-Methylbutyl alcohol 20. 2-Methylbutyl alcohol 21. Ethyl hexanoate


Isobutyl acetate a-Pinene


31. Methyl-para-cresol 32. Ethyl octanoate 33. cis-Linalool oxide 34. Menthone 35. Furfural 36. trans-Linalool oxide 37. Octyl acetate 38. Isomenthone


39. a-Copaene 40. Camphor 41. Benzaldehyde 42. Ethyl nonanoate 43. Linalool 44. Linalyl acetate 45. Vertenex (isomer 1) 46. Octanol


1 2 5 8 6 11 3 4 18 9


29 30


13 10 16 15 23 19,20 21 24 27,28 26 32 35 42 43 41 51


52 6163 65


58


54 55 48


93 62


74 76


676975 78 77


81 86,87 84


83 92 91 96 106 94,95 97 98 99 101 103 102 104 105 37 45,46 100


22. g-Terpinene 23. p-Cymene 24. Hexyl acetate 25. Terpinolene 26. Ethyl heptanoate 27. 2,6-Dimethylhept-5-enal (MelonalTM) 28. Rose oxide, cis-rose 29. Hexanol 30. Rose oxide, trans-rose


47. b-Caryophyllene 48. Vertenex (isomer 2) 49. Terpinen-4-ol 50. Methyl benzoate 51. Hexylene glycol 52. Ethyl decanoate 53. Citronellyl acetate 54. Isoborneol 55. Neral


56. a-Terpineol 57. Geranyl formate 58. Borneol


59. b-Bisabolene 60. Benzyl acetate 61. Neryl acetate 62. Geranial 63. Ethyl undecanoate 64. d-Cadinene


65. Geranyl acetate 66. Citronellol 67. Ethyl dodecanoate 68. Geraniol 69. Benzyl alcohol 70. Geranyl butyrate 71. Nonadecane 72. Benzene ethanol 73. Nonadec-1-ene 74. Florazone (isomer 1) 75. Florazone (isomer 2) 76. Hydroxycitronellal 77. Dodecanol 78. Diphenyl oxide 79. Citronellyl tiglate 80. Eugenyl methyl ether 81. g-Nonalactone 83. Ethyl tetradecanoate 84. n-Amyl salicylate 85. Geranyl tiglate 86. Ethyl pentadecanoate 87. Isopropylmyristate 90. Phenylethyl tiglate 91. Rosatol (rosetone) 92. Eugenyl acetate 93. Ethyl hexadecanoate 94. g-Dodecalactone 95. Dibenzyl ether 96. Tonalid 97. Ethyl octadecanoate 98. Benzophenone 99. Benzyl benzoate 100. Cetearyl octanoate 101. Musk T (ethylene brassylate) 102. Cetearyl decanoate 103. Frambione (raspberry ketone) 104. Cinnamyl phenyl acetate 105. Phenyl ethyl cinnamate 106. Cinnamyl cinnamate


Many thanks to Carl Frey, Manager of Analytical Services, Dragoco, and Kevin Myung, Director of Flavor and Perfumery Research, Bush Boake Allen, Inc. for contributing to this work.


0


10


20


30


40


50 Time (min) 64


60


70


80


90


100 105 GCFF004


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