Food, Flavor, and Fragrance Applications Fragrance Reference Standard I


Column: DB-1 122-1032 30 m x 0.25 mm, 0.25 µm


Carrier: Helium at 25 cm/sec, measured at 150°C Oven: 40°C for 1 min 40-290°C at 5°/min


Injection: Split, 250°C Split ratio 1:50


Detector: MSD, 300°C transfer line Sample: 1 µL of a 1:20 dilution of neat sample in acetone


1. Acetone 2. 2,3-Butanedione (diacetyl) 3. Ethyl acetate 4. 2,3-Pentanedione (acetyl propionyl) 5. Ethyl propionate 6. Methyl butyrate 7. 3-Methylbutyl alcohol 8. 2-Methylbutyl alcohol 9. Isobutyl acetate 10. Ethyl butyrate 11. Furfural 12. Ethyl isovalerate 13. Hexanol 14. Allyl butyrate 15. Ethyl pentanoate 16. Hexylene glycol


17. a-Thujone 18. Benzaldehyde


19. a-Pinene 20. Camphene 21. 3,5,5-Trimethylhexanol 22. Sabinene


23. b-Pinene 24. Ethyl hexanoate 25. Myrcene 26. Hexyl acetate cis-Linalool oxide Methyl benzoate trans-Linalool oxide


3 2 1 7 5 9 10 12 126 15 4 11 14 13 16 18 21 8 20 26 24


30 32


29 33 35


37 38 41


44 42 47 58 70 49 54 53 61, 62 63 73 71 74


78 77 81


80 89 100 101 88 90 98 91 93 96 102 103 105 110 108 111 115, 116 118 113 120 117 123 122 124 125 127 6 67, 68


28. Methyl-cresol 29. Benzyl alcohol 30. para-Cymene 31. 1,8-Cineol 32. Limonene 33. 2,6-Dimethylhept-5-enal


34. g-Terpinene 35. Octanol 37. Ethyl heptanoate 38. Linalool 39. Benzene ethanol 41. Rose oxide, cis-rose 42. Rose oxide, trans-rose 43. Camphor 44. Citronellal 45. Benzyl acetate 46. Menthone 47. Isoborneol 48. Isomenthone 49. Borneol 51. Terpinen-4-ol


52. a-Terpineol 53. Ethyl octanoate 54. Octyl acetate 56. Fenchyl acetate 57. Citronellol 58. Neral 59. Carvonel Phenylethyl acetate


Many thanks to Carl Frey, Manager of Analytical Services, Dragoco, and Kevin Myung, Director of Flavor and Perfumery Research, Bush Boake Allen, Inc. for contributing to this work.


Suggested Supplies


Septum: Advanced Green, 5183-4759 Liner: Split, single taper, low pressure drop, glass wool, 5183-4647


Seal: Gold plated seal, 18740-20885 Syringe: 5 µL tapered, FN 23-26s/42/HP, 5181-1273


60. Geraniol 61. Linalyl acetate 62. Geranial 63. Hydroxycitronellal 64. Citronellyl formate 66. Bornyl acetate 67. Vertenex (isomer 1) 68. Ethyl nonanoate 69. Geranyl formate 70. Vertenex (isomer 2)


71. g-Nonalactone 72. Citronellyl acetate 73. Neryl acetate 74. Geranyl acetate 76. Diphenyl oxide 78. Ethyl decanoate


96. Rosatol (rosetone) Geranyl butyrate


97. trans-Nerolidol 98. n-Amyl salicylate 99. Phenylethyl tiglate 100. Ethyl dodecanoate 101. Benzophenone 102. Dibenzyl ether


79. a-Copaene 80. Florazone (isomer 1) 81. Florazone (isomer 2)


89. Ethyl undecanoate 90. Eugenyl acetate 91. Frambione (raspberry ketone)


93. Isoamyl salicylate


94. d-Cadinene 95. cis-Nerolidol


82. b-Caryophyllene 83. Citronellyl propionate 85. 3,7-Guaiadiene 88. Dodecanol


109. Heptadec-1-ene 110. Benzyl benzoate 111. Ethyl tetradecanoate 112. Benzyl salicylate 113. Tonalid 114. Nonadec-1-ene 115. Isopropylmyristate 116. Ethyl pentadecanoate Nonadecane


103. g-Dodecalactone 104. Citronellyl tiglate 105. Evernyl 106. Geranyl tiglate 107. Geranyl-2-methyl valerate 108. Celestocide


117. Ethyl hexadecanoate 118. Musk T (ethylene brassylate) 119. Eicosane 120. Cinnamyl phenyl acetate 121. Heneicosane 122. Phenyl ethyl cinnamate 123. Ethyl octadecanoate 124. Hercolyn D (tetrahydro & dihydro methyl abietate)


125. Cinnamyl cinnamate 126. Cetearyl octanoate 127. Cetearyl decanoate


0


5


10


15


20


25 Time (min) Order online at www.agilent.com/chem/store


30


35


40


45


50 GCFF003 63


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