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7. Haryanto, A.; Lee, C. W. Shell Isolated Nanoparticle Enhanced Raman Spectroscopy for Mechanistic Investigation of Electrochemical Reactions. Nano Convergence 2022, 9 (1), 9. DOI:10.1186/s40580-022-00301-1


8. Zong, C.; Xu, M.; Xu, L.-J.; et al. Surface-Enhanced Raman Spectroscopy for Bioanalysis: Reliability and Challenges. Chem. Rev. 2018, 118 (10), 4946–4980. DOI:10.1021/acs. chemrev.7b00668


9. Hartman, T.; Wondergem, C. S.; Kumar, N.; et al. Surface- and Tip-Enhanced Raman Spectroscopy in Catalysis. J. Phys. Chem. Lett. 2016, 7 (8), 1570–1584. DOI:10.1021/acs.jpclett.6b00147


10. Wu, D.-Y.; Li, J.-F.; Ren, B.; et al. Electrochemical Surface-Enhanced Raman Spectroscopy of Nanostructures.Chem. Soc. Rev. 2008, 37 (5), 1025–1041. DOI:10.1039/B707872M


11. Zhao, X.; Wen, J.; Zhu, A.; et al. Manipulation and Applications of Hotspots in Nanostructured Surfaces and Thin Films. Nanomaterials 2020, 10 (9), 1667. DOI:10.3390/ nano10091667


12. Zhu, M.; Li, M.; Su, M.; et al. Can “Hot Spots” Be Stable Enough for Surface-Enhanced Raman Scattering? J. Phys. Chem. C 2021, 125 (24), 13443–13448. DOI:10.1021/acs. jpcc.1c03321


13. Li, J. F.; Huang, Y. F.; Ding, Y.; et al. Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy. Nature 2010, 464 (7287), 392–395. DOI:10.1038/nature08907


14. Gellrich, F. Electrochemical and Spectroelectrochemical Characterization of Electrocatalysts for the Alkaline Water Electrolysis; DTU Energy: Kgs. Lyngby, Denmark, 2021.


15. Cole, K. M.; Kirk, D. W.; Thorpe, S. J. In Situ Raman Study of Amorphous and Crystalline Ni-Co Alloys for the Alkaline Oxygen Evolution Reaction. J. Electrochem. Soc. 2018, 165 (15), J3122. DOI:10.1149/2.0131815jes


16. Faid, A. Y.; Barnett, A. O.; Seland, F.; et al. Ni/NiO Nanosheets for Alkaline Hydrogen Evolution Reaction: In Situ Electrochemical-Raman Study. Electrochimica Acta 2020, 361, 137040. DOI:10.1016/j.electacta.2020.137040


Read, Share and Comment on this Article, visit: www.labmate-online.com/article LDIR Chemical Imaging System for Microplastics Analysis


The enhanced 8700 LDIR Chemical Imaging System from Agilent Technologies has been further optimised for the analysis of microplastics in environmental samples. This newly improved package includes Clarity 1.5 software - a signifi cant upgrade that advances the speed of analysis, enhances spectral acquisition, transformation, and library matching, and provides automated workfl ows for direct analysis of microplastics on a fi lter substrate. An innovative, redesigned sample holder allows the on-fi lter sample to be presented to the instrument more easily and consistently.


Slow and complex analysis solutions are a major challenge to microplastics analysis and have hindered studies of real-world systems. Additionally, method variability limits the comparability of studies, making trends diffi cult to assess. Vibrational spectroscopy methods such as FTIR and Raman microscopy provide a useful alternative, but each faces limitations due to the excessive time of analysis and method complexity.


The Agilent 8700 LDIR brings high-speed analysis and ease of use to infrared spectroscopy and has rapidly emerged as the benchmark technique for the analysis of microplastics particles. The development of on-fi lter analysis for this platform marks another leap forward in speed and throughput. The ability to signifi cantly increase testing volumes will allow a greater understanding of the extent of microplastics contamination in the environment and will help facilitate the development of appropriate standards and regulations.


Geoff Winkett, Vice President and General Manager for Agilent’s Molecular Spectroscopy Division, discussed the announcement’s impact. “When I speak with microplastics researchers, a recurring question is how to make testing faster and easier, as there is a real concern that the limited sample numbers that can be realistically processed may be masking the true nature of the issue,” he said. “The fact is that other currently available techniques are too slow and cannot capture the extent of the microplastics load in drinking and environmental waters. Fast and easy-to-use analysis methods such as the 8700 LDIR provide an essential and much-needed alternative that enables researchers to increase sampling over area or time to address these limitations.”


More information online: ilmt.co/PL/30y0 58920pr@reply-direct.com


New Process Gas Analysis Brochure


Hiden Analytical develops and supplies instruments for a new era of process gas analysis from UHV to Atmospheric Pressure. The latest in the range of product showcase brochures, HPR-30 Series offers an insight into the range of instruments, sampling inlets and software packages.


The Hiden HPR-30 Series are bolt on vacuum process analysers designed for fast response, high sensitivity analysis of gas and vapour species. Equipped with Hiden’s multi-level software package, offering simple control of mass spectrometer parameters and complex manipulation of data and control of external devices. Applications include leak detection, contamination monitoring, process trend analysis and analysis of high mass species and precursors used in ALD and MOCVD. Standard mass range is 200 amu, versions up to 1000 amu are offered.


Optional upgrades include the innovative Hiden 3F series triple fi lter quadrupole system providing enhanced abundance sensitivity, part- per-billion (ppb) detection levels and high contamination resistance, particularly suited to the analysis of aggressive gases in CVD and RIE applications. Standard mass range is 200 amu, versions up to 1000 amu are offered.


Multiple sampling confi gurations are offered to suit a full range of process pressure and vacuum system geometry requirements. Versions are offered with single, or multiple sampling inlets, either unheated or heated to allow sampling of volatile species.


Systems are offered cart mounted, and with height adjustment for maximum compatibility between tools. For pulsed deposition processes, time resolved measurements are offered to 50 ns time resolution.


The HPR-30 Series are designed to offer a fully featured, fl exible and powerful solution for the monitoring of parameters in all aspects of process gas analysis such as leak detection, vacuum quality and precursor monitoring.


More information online: ilmt.co/PL/D3kL 59240pr@reply-direct.com


Interested in publishing a Technical Article?


Contact Gwyneth on +44 (0)1727 855574


or email: gwyneth@intlabmate.com Our articles are read by over 73,000 readers in print, online and via our Mobile App.


LAB ASIA - FEBRUARY 2023


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