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Lithium-Air Battery Progress is Breathtaking


S


cientists at UK’s University of Cambridge have devel- oped a working laboratory demonstrator of a lithium-ox- ygen battery that has very high energy density, is more than 90% effi cient, and, to date, can be recharged more than 2000 times, showing how several of the problems holding back the development of these devices could be solved. Lithium-oxygen, or lithium-air, batteries have a theoretical energy density that’s ten times that of a lithium-ion battery. Such a high energy density would be comparable to that of gasoline–and would enable an electric car with a battery that is a fi fth the cost and a fi fth the weight of those currently on the market to drive over 400 miles on a single charge—theoretical- ly, that is. However, as is the case with other next-generation batteries, there are several practical challenges that need to be addressed before lithium-air batteries become a viable alterna- tive to gasoline.


Microscope image showing charged (left) and discharged graphene electrodes.


University of Cambridge researchers have now demon- strated how some of these obstacles may be overcome, and developed a lab-based demonstrator of a lithium-oxygen battery which has higher capacity, increased energy ef- fi ciency and improved stability over previous attempts. Their research was published in the journal Science. What Tao Liu, Clare Grey and their colleagues at Cam- bridge have developed uses a different chemistry than earlier attempts at a nonaqueous lithium-air battery, relying on lithium hydroxide (LiOH) instead of lithium peroxide (Li2


O2 ).


With the addition of water and the use of lithium iodide as a ‘mediator’, their battery showed far less of the chemical


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Image courtesy University of Cambridge


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