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had a similar trend, but the aver- age and maximum values mainly depended on the phase of starting materials and the thermal pro- cessing’s reactions and transfor- mations, which were not readily predicable. The investment casting shells, where colloidal silica was used


as a binder in most cases and a significant amount of fused silica was utilized as flour and stucco, more often showed increasing thermal conductivity at higher temperatures. Porosity had a significant influence on thermal conductivity. Between the two aluminosilicate


shells (4 and 6), 6 had the higher total porosity (37.65%) and exhib- ited lower thermal conductivity values throughout the measured temperature range. Another good example is the


weak temperature dependence of conductivity in the alumina-based shell (5). Since the photon radia- tion in alumina is not significant until 1,832F (1,000C), this radia- tion compensates phonon scatter- ing in alumina and the porosity effects, and consequently the


Fig. 5. The graphs show the comparison of values determined by the inverse and improved laser flash methods for shells 3 (a), 4 (b); 5 (c) and 6 (d).


42 | MODERN CASTING January 2015


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