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Nembutal continues to be sold over-the-counter and over the Internet from several countries around the world.
However, while the purchase of Nembutal might be quick and legal in some countries, the importation of Nembutal to your home country is almost certainly illegal and may attract penalties. You would need to check the particular laws of the jurisdiction in which you reside to be certain.
However, if a seriously ill person purchases Nembutal lawfully in one country and then takes the drug and ends their life in that country, it is likely no laws will be broken.