Now, shipbuilding quality mild steel is a type of carbon steel containing a very low amount of carbon and the amount of carbon typically found in such metal is only 0.23% by weight. Steel is not an iron alloy and, further, does not contain large amounts of other elements such as chromium, molybdenum or manganese, although all of those can be found as trace elements together with small amounts of sulphur and phosphorus. Since its carbon and alloying element content are relatively low, there are several properties it has that differentiate it from the higher carbon and alloy steels. Less carbon means that mild steel is typically more ductile, machinable and weldable than high carbon and other steels, but that also means it is nearly impossible to harden and strengthen through heating and quenching. The low carbon content also means that the carbon and other alloying elements do not block dislocations in its crystal structure, generally resulting in a lower tensile strength than the high carbon and alloy steels. Mild steel also has a high amount of iron and ferrite, making it magnetic. The carbon is usually found in carbide crystals of pearlite and cementite. Both those crystals are cathodic to those of the ferrite, so that when unprotected steel is placed in an electrolyte such as canal, river or sea water, a galvanic cell is set up between them causing the ferrite to dissolve forming deep pits over the steel surface. In order to prevent the resulting damage, the steel has to be properly coated with a protective paint and fitted with a suitable type and number of anodes. The strength of that galvanic current is, inter alia, a function of the conductivity of the water and that, in turn, is a function of the water’s salinity or impurity. The particles that make up that current also possess mass and are, therefore, controlled not only by Ohm’s law but also by Newton’s laws of motion and a properly designed (not guessed) cathodic protection scheme has to take that fact into account.
Ohm’s law is a formula used to calculate the relationship between voltage, current and resistance in an electrical circuit and is named after German physicist Georg Ohm (1789- 1854). It addresses the key quantities at work in simple electric circuits.
Symbolically, it states that: V
= where I
R V
The formula is
usually demonstrated graphically as a triangle as in Figure 1.
Volts Amps Ohms
Figure 1 - The Ohm’s Law Triangle
R where
A L
R ρ
= = = =
the area of the electrical path The length of that path the resistance
the specific resistance
Effectively that means that the area over which the anode provides cover is limited and that fact decides the distance over which an anode will work and, therefore, the distance apart that anodes must be fitted.
Sir Isaac Newton (25th 1642 – 20th
December March,1726) who is
widely recognised as one of the greatest of mathematicians and most influential of scientists, first published his three laws of motion in his book Philosophiae Naturalis Principia Mathematica in 1687. The first of those laws states that if a body is at rest or moving at a constant speed in a straight line, it will remain at rest or keep moving in a straight line at constant speed unless it is acted upon by another force. The postulate is also known as the law of inertia and was first formulated by Galileo for horizontal motion on Earth and later generalized by Descartes. Before Galileo, it had been thought that all horizontal motion required a direct cause, but Galileo deduced from his experiments that a body in motion would remain in motion unless a force (such as friction) caused it to come to rest.
• a moving object continues to move at the same velocity and in the same direction.
Those two laws have a number of clear implications for the effectiveness of an anode.
Ohm’s law means that as the only force acting on one of the particles making up the current is the algebraic sum of the potential difference between the anode, the cathode and the resistance offered by the electrolyte (the water in which the vessel floats), there is a definite limit to the area over which the anode can be effective. It must also be clearly understood by the marine surveyor that that effective area over which the anode works, is a function of the wetted surface area of the anode
The Report • June 2021 • Issue 96 | 105
mm2 m
ohms ohms/mm.m
According to that law, an object remains in the same state of motion unless a resultant force acts on it. If the resultant force on an object is zero, then:
• a stationary object remains stationary,
= ρL/A
If two of those three factors are known, then the third is easily calculated.
The resistance in the circuit is governed by the equation: -
ohms (2)
= = =
The current in the circuit
The resistance encountered by the current ohms The potential difference in the circuit
amps volts
I x R
(1)
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