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with the nitrogen deep acceptor in fact
Nitrogen cannot dope ZnO
occurs at much lower energies, at
wavelengths that have been all but ignored
in prior studies. When it comes to electrical
p-type, say UCSB researchers
measurements of acceptor-doped ZnO, the
researchers point out there are many
potential pitfalls, casting doubt on the p-
COMPUTATIONAL scientists at the However, independent verification of these type conductivity reports published to date.
University of California, Santa Barbara reports has been lacking, as have
(UCSB), have provided convincing evidence convincing demonstrations of pn junctions. “We are convinced that none of the
that nitrogen, which is widely believed to be substitutional acceptors (including Li, N, P,
a shallow acceptor in ZnO, is in fact a very The UCSB team, consisting of John Lyons, As, or Sb) will yield p-type conduction”
deep acceptor and cannot lead to p-type Anderson Janotti, and Professor Chris Van commented Project Scientist Anderson
conductivity. de Walle, performed calculations based on Janotti. “Interstitial doping still looks
the hybrid functional methodology. In an promising, although it may be difficult to
ZnO has been intensively pursued as an Applied Physics Letter published online it is accomplish in actual device fabrication.”
optoelectronic material, in hopes of reported that nitrogen acceptors have an
developing it into a wide-band-gap light ionization energy of 1.3 eV-much too large “Our finding that nitrogen is not a shallow
emitter that would compete with GaN-but to enable p-type doping. acceptor will come as a disappointment to
with the advantage that large single-crystal many who are excited about ZnO as an
substrates are commercially available. A They also address why the behaviour of optoelectronic material” said Van de Walle.
large part of the effort has been directed at nitrogen has been misinterpreted in so many “However, we hope it will contribute to
establishing p-type doping, which is very of the previous investigations. In optical resolving the conflicting results that have
challenging in wide-band-gap oxides in studies, the photoluminescence line most plagued the literature, and will refocus ZnO
general. Dozens of papers claiming commonly associated with nitrogen is now research efforts on the many exciting
observations of p-type conductivity have known to be caused by stacking faults. applications that do not require ambipolar
appeared in the scientific literature. Optical absorption and emission associated doping, such as transistors and sensors.”
RABOUTET
Iron-arsenic compounds sought
S.A.
Manufacturer of Molybdenum.
for quantum critical point
Components for MBE.
THE ABILITY of electrons to magnetic quantum critical point
Specialized Cleaning
conduct electricity with no can be found in these materials,
& Degassing available.
resistance is linked to their something which could prove
magnetic properties, new essential to the future
research has revealed. development of semiconductors.
A recently-discovered class of The researchers noted that high-
iron-based superconductors have temperature superconductors
undergone experiments by a team could be used to progress MRI
of Chinese and US physicists scanners, high-speed trains and
who discovered that the ability of electric generators.
electrons being able to conduct
electricity with no resistance is Mr Si stated: “The evidence from
specifically linked to their this study bolsters the hypothesis
magnetic properties. that high-temperature
superconductivity in the iron
Rice University revealed in a pnictides originates from
recent edition of Physical Review electronic magnetism.”
RABOUTET S.A.
Letters that close examination of
250 Av Louis Armand
several iron-arsenide compounds Low temp superconductivity is
Z.I Des Grand Prés
found that the strength of the caused by ionic vibrations. Last
F-74300 Cluses France
magnetic order was reduced year, Ames Laboratory research
when smaller phosphorus atoms revealed that iron-arsenide
Tél : 33 (0)4 50 98 15 18
were introduced and replaced the semiconductors’ ability to carry a
Fax : 33 (0)4 50 98 92 57
arsenic atoms. viable current could hold potential
E-mail : info@raboutet.fr
for the future development of
http://www.raboutet.fr
Qimiao Si, a Rice physicist, said much sought after zero-resistance
this highlights evidence that a power transmission.
8 www.compoundsemiconductor.net January/February 2010
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