literature is notably scant on the multitude of complex chemical reactions that occur during re-refining.
It should be noted that cold solvent extraction using liquid propane is another option to remove contaminants, while some high pressure hydrotreatment processes can complete a number of reactions in one step, whereas other processes require several.
One important aim of processing is to ensure any polycyclic aromatic hydrocarbons (PAHs) introduced during the lubricants use, from partly combusted fuels, are removed to meet requisite toxicological standards including the IP346 test of 3% specified PAH’s max.
For general guidance, the yield from a range of re-refining processes on dry feedstock is typically around 70% base oils, where the viscosity outputs are largely dependent on the feedstock type and fractionation set up, 10% light fuel of a gas oil type, and the remaining balance comprised of a heavy residue, often used in asphalt or bitumen products as an alternative flux oil.
A detailed account of the quality and environmental benefits of re-refining ULOs to obtain base oils and other streams will be included in articles three and
four of this series, but here it is highlighted that on a well to wheel basis, carbon savings form a large part of the re-refining sustainability feature. With the range of re-refining treatments available to quote a single carbon life cycle figure would be inappropriate, but studies to ISO 14040/14044 guidelines show considerable savings ranging from 364-549 kg CO2
-eq./t of waste oil.
The key message is that re-refiners have mastered the processing experience of traditional base oil refining to manage the removal from used oils of a different range of unwanted contaminants, compared with those in crude oils, without detracting from the market requirement to provide base oils of the character originally described by the globally recognised API Group classifications. They do so in a sustainable manner with large carbon savings relative to that of other energy recovery options.
This article was produced by Slicker Recycling Limited and its joint venture partner, Avista Green.
www.slickerrecycling.com
avistagreen.dk
LUBE MAGAZINE NO.177 OCTOBER 2023
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