Gas Detection 37


latest carbon monoxide sensor, 4CM, offers the fastest response and recovery times in the industry. City’s Pellistors are robust, poison-resistant and offer outstanding shock and vibration immunity, a critical requirement for the mining industry.


Superficially, a gas sensor might appear to the untrained eye to be no more than a simple small cylinder, 20mm in diameter and 17mm high, with two or three electrodes. In fact, nothing could be further from the truth. Such an unremarkable looking component is the operating heart of all gas detection equipment, which saves countless lives and prevents damage to property worth billions of dollars.


Oxygen Sensors


self-evident. Bump testing for personal gas detection equipment, in which the instrument is exposed to its target gas to check for correct operation, would normally take place on the surface. Descending in high speed lifts to the working levels will result in rapid increases in temperature and humidity, potentially causing the instrument to false alarm, with a consequent loss of time and confidence while the issue is sorted out. Instruments fitted with 4OXV do not suffer from such issues, improving efficiency and reducing down time.


Carbon Monoxide Sensors


“Speed is of the essence”. A truism applied to many different situations, but a statement that is arguably critical in mining life safety applications, where delay can literally prove to be fatal. Carbon monoxide, a colourless, odourless, tasteless, and initially non-irritating gas is very difficult for people to detect. Exposure to 100 ppm or greater can be dangerous to human health, and as the symptoms of mild exposure include light-headedness and confusion, while larger exposures can lead to death, the provision of an effective CO detector is an imperative for personnel who may encounter it during the course of their work. CO is commonly found in mines, so a fast and effective CO detector is an essential piece of equipment.


Gas sensors are in fact complex pieces of equipment: 4OXV, the new oxygen sensor, is constructed from more than 20 individual components, which are manufactured to exceedingly tight tolerances and assembled to create the finished product on an automated assembly and test line. As an example of the technology behind the design of gas sensors, consider the 4OXV oxygen sensor that is used in portable gas detectors in mines. It features City’s field-proven and highly successful vented liquid electrolyte technology, which includes a unique pressure equalising vented design. The sensor’s internal anti-bulkflow mechanism eliminates false alarms and further dampens the response to transient pressure changes. The design also minimises threshold drift in slow temperature and pressure variations, providing the maximum possible headroom between the quiescent state and alarm levels. Humidity changes are another significant cause of false alarms. 4OXV features an integrated moisture protection membrane to prevent the ingress of humid air into the chamber. The implications in the mining environment are


City’s new 4CM sensor meets the Chinese mining specification, AQ6205-2006, widely regarded as the most severe set of requirements to be found anywhere in the world. Since its launch in early 2012, 4CM has been specified by more than twenty major instrument manufacturers who supply detectors for use in Chinese mines; more than fifty thousand units are now in service. 4CM reacts 12% faster to CO hazards than other sensors on the market; with a typical T90 time of seven seconds, giving users critical extra time in the event of an emergency. The recovery time is equally impressive, returning to an indicated level of <2ppm in under 100 seconds, less than half the time of alternatives. Worker downtime is reduced, as they do not have to wait so long for the instrument to recover. During prolonged 50-day exposures in 50°C and 11% relative humidity, hot and dry conditions and when exposed to 50°C at 95% relative humidity for 50 days, in hot and wet environments, the 4CM continues to operate to specification.


Flammable and Explosive Gas Sensors


In addition to being used in personal gas detection equipment, City supplies sensors, typically pellistors, used to detect combustible gases, which are installed in ruggedised gas detectors


Meeting Global and Regional Requirements


City sensors are to be found in detection equipment used in the world’s main coal mining regions. The top four regions are China, which in 2011 accounted for just under 50% of world coal production, the USA with a 14% share, India which accounts for 6% and Europe, 4%. Methane is arguably the most dangerous gas in mining, present both in the mines themselves and also in coal washeries. City has an extensive range of methane and flammable gas sensors that carry approvals from the various mining specification authorities. Some markets also have specific requirements. For example, in South Africa, hydrogen cross- sensitivity is a major issue for CO and methane sensors, in Indian surface mines H2S is a major hazard.


The Future


Without doubt, today’s sophisticated gas detection technology has saved many lives in what is still one of the world’s most dangerous industries. Gas detection instrument manufacturers typically rely on gas sensors from specialist manufacturers. Typically based on electrochemical technology, the characteristics of the gas sensor itself determine, to a great extent, the instrument’s performance and reliability in use. To offer their users reduced lifetime cost of ownership, enhanced performance and features that improve the functionality, reliability and effectiveness of personal and fixed gas detection, OEMs require the gas sensor manufacturers to innovate sensors that have better stability, greater resistance to cross- contamination, longer life and faster response. City has a long tradition of developing new products that make a positive contribution to life preservation, with particular emphasis on meeting the unique demands of the coal mining industry, still one the world’s most hostile working environments, particularly in less developed and emerging economies.


positioned on walls and machinery in mines. They are frequently installed on underground vehicles where they are subject to high levels of shock and vibration during normal operation, so for reliable operation pellistors have to be mechanically robust as well as highly resistant to cross contamination from commonly occurring poison sources. The pellistor was originally developed as a far safer replacement for the flame safety lamp hitherto used as a flammable gas detector once battery lighting had replaced a naked flame as a source of illumination. The flame safety lamp itself was invented by Davy and Stephenson to replace the even more dangerous open candle flames previously used for illumination.


NASA uses Portable FTIR Gas Analyser with Leonardo MPLM-1 Module


Keeping pace with NASA’s International Space program is no easy feat. However Gasmet Technologies (Finland) with the world’s first truly portable FTIR gas analyser put in long hours in its role of testing the air quality from NASA’s Leonardo MPLM, also known as MPLM-1 (Multi-Purpose Logistics Module). The MPLM-1 is one of three modules operated by NASA to transfer supplies and equipment to and from the International Space Station.


Providing real-time measurements of up to 25 toxic gases simultaneously, the portable DX-4030 analyser wirelessly transferred gas readings from the analyser housed in a backpack to a handheld rugged PDA by Bluetooth communication. The operator controlled the operation of the DX-4030 via the Calcmet-Lite software running on the Windows mobile platform. Gas readings were easily viewed and recorded and independent audible gas alarms were pre-programmed for each gas. Supplementary to grab samples taken with evacuated canisters, the DX-4030 FTIR gas analyser gave the NASA scientists real-time readings with sub-ppm detection levels of inorganic and organic gases such as Carbon Monoxide, Carbon Dioxide, Ammonia, Acids and Aldehydes and other VOC’s in the module’s airspace.


An inherent advantage of the FTIR measurement technology is its low cost of ownership requiring only a short zero calibration before using the analyser each day. No other routine calibration or expensive consumables are required.


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WORLD CLASS SPECIALISTS


IN GAS MEASUREMENT


Via Cesare Battisti 50-D 24046 - Osio Sotto (BG) ITALY Tel. (+39) 035-482.39.39 Fax. (+39) 035-482.37.79


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