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12-01 :: January 2012

nanotimes News in Brief Graphene //

NIST Theorists Quantify the Friction of Graphene © Based on Material by NIST

S

imilar to the way pavement, softened by a hot sun, will slow down a car, graphene slows down

an object sliding across its surface. But stack the sheets and graphene gets more slippery, say theorists at the National Institute of Standards and Techno- logy (NIST), who developed new software to quan- tify the material‘s friction.

“I don‘t think anyone expects graphene to behave like a surface of a three-dimensional material, but our simulation for the first time explains the diffe- rences at an atomic scale,” says NIST postdoctoral researcher Alex Smolyanitsky, who wrote the mo- deling program and co-authored a new paper about the study. “If people want to use graphene as a solid-state lubricant or even as a part of flexible electrodes, this is important work.”

With the capacity to be folded, rolled or stacked, graphene is super-strong and has unusual electronic and optical properties. The material might be used in applications ranging from electronic circuits to solar cells to “greasing” moving parts in nanoscale devices. Friction is the force that resists the sliding of two surfaces against each other. Studying friction at the atomic scale is a challenge, surmountable in only the past few years. The NIST software simulates atomic force microscopy (AFM) using a molecular dynamics technique. The program was used to measure what happens when a simulated AFM tip moves across a

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NIST software simulates the tip of an atomic force microscope moving left across a stack of four sheets of graphene. Research using this software indicates that graphene‘s friction is reduced as more layers are added to the stack. © A Smolyanitsky/NIST

stack of one to four graphene sheets (see image) at different scanning rates.

The researchers found that graphene deflects under and around the AFM tip. The localized, temporary warping creates rolling friction or resistance, the force that exerts drag on a circular object rolling along a surface. Smolyanitsky compares the effect to the sun melting and softening pavement in the state where he got his doctoral degree, Arizona, causing car tires to sink in slightly and slow down. The NIST

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