FEATURE SMART BUILDINGS & IOT
ENERGISING HEAT FOR SMART APPLIANCES S
cientists are getting closer to designing thermoelectric materials
that efficiently harvest heat from the surrounding environment and convert it into electricity to power various devices and appliances, according to a review of the latest research in the journal Science and Technology of Advanced Materials. Devices made with these materials could avoid the need to recharge, change and dispose of batteries. For thermoelectric materials to be efficient energy producers, they need to be able to hold heat and conduct electricity well. Thermoelectric materials that can work near room temperature and are flexible would be especially advantageous, particularly for use in wearable devices. Three types of conducting materials are being investigated for use in thermoelectric devices: inorganic, organic and hybrid materials. Inorganic thermoelectric materials efficiently convert heat into electricity, but are not very flexible. Researchers are working to overcome
this hurdle. For example, a flexible thermoelectric device was fabricated
using chromel (90 per cent nickel and 10 per cent chromium) and constantan (55 per cent copper and 45 per cent nickel) layers covered by a flexible sheet made of polyimide and copper. Micro- thermoelectric generators based on inorganic materials have potential applications in environmental and building monitoring, animal tracking, security and surveillance, and medical treatment. They have already been introduced into commercial devices, such as a body-heat-powered watch manufactured by Seiko. Most organic thermoelectric devices
involve polymers. Semiconducting polymers conduct electricity and hold heat better than conventional inorganic semiconductors. They are also lighter and less expensive. Unlike rigid inorganic materials, they are flexible and moldable and can be produced in any shape using 3D printers. However, they are less efficient at converting heat into electricity. Researchers are trying to improve the thermoelectric efficiency of polymers by tuning the composition, length and arrangement of their molecules, aiming to increase the
electrical conductivity and crystallinity of the final material. Research that aims to combine the advantages of organic and inorganic materials by blending them together is focused on finding optimal compositions and improving the mixing process. For example, embedding organic molecules into inorganic titanium disulfide crystals makes them flexible and reduces their thermal conductivity. This improves the overall thermoelectric performance.
Science & Technology of Advanced Materials
tandfonline.com
Electrical Engineering in the palm of your hand
32 DECEMBER/ JANUARY 2019 | ELECTRICAL ENGINEERING
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