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BATTERIES & CHARGERS
LITHIUM-ION SAFETY L
ithium-ion batteries are found in virtually all types of electrical and electronic devices, including advanced industrial equipment. This is because they offer several advantages over conventional batteries, including greater energy density and cell voltage, and little charging capacity loss over time for rechargeable batteries. There are three major configurations for Lithium-ion batteries:
The small format - batteries we are used to seeing in electronic devices and hand tools.
Larger batteries - used in mobile equipment such as lift trucks and vehicles.
Very large-scale Energy Storage Systems - typically used for uninterruptible power supplies or for electric power grid storage, often in conjunction with renewable power generation equipment.
Each lithium-ion battery consists of cells, in which lithium is the agent for an electrochemical reaction that produces energy. When discharging, lithium ions in the battery cell move from the anode (the negative electrode) to the cathode (the positive electrode) through an electrolytic substance, which is typically a liquid or gel and results in the release of energy from the battery. The process is reversed when the battery is being charged, with ions moving from the cathode to the anode.
MITIGATING RISKS
While technology development has advanced over the last few decades, it has also presented new fire and explosion risks. For industrial environments, the proper storage and risk management of lithium-ion batteries is therefore critical, and there are a wide range of safety standards, including
18 Autumn 2023 UKManufacturing
IEC 62133, UN/DOT 38.3 and IEC 62619. As well as many benefits, there are potential safety risks related to thermal stability and internal short circuits. Safety problems arise due to poor design, the use of low-quality materials, incorrect assembly, or damage. Even for lithium-ion batteries with integrated safety features, an unanticipated breach in the battery separator material can result in a high current that overheats the battery’s electrolyte. While battery manufacturers and developers are continually improving lithium-ion battery design and performance, this can make them more vulnerable to small manufacturing defects or internal damage from the physical impact with another object. Variations in battery design, and the quality of materials and manufacture can also cause potential safety risks. Of course, this problem will be magnified if large quantities of batteries are stored on- site or transported between industrial facilities. Fortunately, there are important steps that operators of industrial facilities can take to reduce the risks. For example, idle batteries in storage are not typically subject to internal ignition. However, large-scale testing has shown that lithium-ion batteries behave similarly to unexpanded plastic commodities in a fire. Therefore, sprinkler protection should be provided. Fully charged lithium-ion batteries have a higher energy density and are therefore at greater risk of generating significant heat from short circuiting caused by internal defects. It is therefore important to ensure that lithium-ion batteries stored in the longer-term are charged at levels below 50 per cent charge capacity and kept at temperatures between 4-27°C. This will help to minimise the risk of thermal runaway from manufacturing defects or internal failures. While usually safe, as lithium-ion battery charging can cause safety problems, stations
By Marcus Sampson, business line manager for Transport at TÜV SÜD
designated for charging large format batteries should be separated from other combustible materials by at least one metre. For larger format batteries, such as those used in mobile equipment, battery chargers and batteries being charged should be separated from other combustible contents by at least one metre. Stations used for charging small format batteries should be set on a firm, non-combustible surface and be separated from other combustible materials by at least 30 centimetres. Before disposing of damaged or unwanted lithium-ion batteries, in waste bins for example, their battery terminals should be covered with insulating material. This will help to ensure that the terminals do not accidentally come in contact with metal or other battery contacts that could close the battery circuit and result in an unintended energy discharge.
Likewise, bins holding damaged or discarded batteries should be separated by at least three metres from all other storage areas, as well as bins holding other potentially combustible
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