FLAME RETARDANTS | ADDITIVES
developing formulations to pilot.” Graphene is also proving to be an interesting option for improving flame retardance in thermo- plastics. Not so long ago, graphene was consid- ered a very exotic material with very high costs to go with it. However, new production technologies are bringing it closer to the mainstream.
Nano innovation Netherlands-headquartered MPI Chemie says when graphene is used in formulations already containing organic flame retardants, the improve- ment to the flame retardant properties is very promising. “An increase of the Limiting Oxygen Index (LOI) of 9 was observed at one of our customers solely through the addition of graphene. This is a statistically significant finding, but further research needs to be done,” says Sales Manager Jochem Krijnen. “Low dosing, around 1-2% of graphene, could allow for reducing the amount of other FR additives in a compound, thus reducing cost, improving mechanical properties and resulting in a more sustainable solution,” he says. “Our graphene sourcing partner, NanoXplore, is the world’s largest
producer, with a capacity of 4000t/yr, which delivers the economics of scale to allow many commercially viable and cost-effective applications.” A potential downside is that graphene isn’t suitable for light and bright coloured applications due to its anthracite colour, Krijnen says. “However, this may serve as a benefit by allowing the reduc- tion or removal of carbon black, which is a hot topic due to the CO2
footprint that inherently comes with the use of carbon black.” CO2 emis-
sions associated with graphene production are said to be 80% less than those of the same weight of carbon black. HFFR supplier Huber Advanced Materials
reports on a development project for flame retardant wire and cable compounds based on polyolefin elastomers (POEs) that it has conducted in partnership with ExxonMobil. This aimed to evaluate ExxonMobil’s POEs as a polymer carrier alternative to ethylene-vinyl acetate (EVA) in HFFR formulations.
Huber says use of POE in HFFR formulations
requires fine-tuning and higher levels of flame retardant in order to achieve the performance typical of EVA-based HFFR W&C formulations. The
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