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BIOPLASTICS | MATERIALS


Jennifer Markarian investigates new materials and additives used in bio-based plastic compounds along with the launch of biomass-balanced polymers


Emerging bioplastics show better performance


Bioplastics are a diverse category of thermoplastics made from bio-based feedstocks. Some bioplastics are biodegradable (able to biodegrade under specific conditions, such as in industrial compost- ing), while others are not. Because a primary reason for using these materials is to help achieve sustainability goals, both the end-of-life plan and the ability to use renewable (rather than fossil- based) starting materials are important. Terms to explain the types of plastics in the bioplastics category are in flux and not always used consistently. A commonly used definition is that “bio-based” polymers are those made from renewable carbon (from plant, animal, or fungal sources) that can be identified and quantified using a radiocarbon (C14) method, such as ASTM D6866 or ISO 16620-2, rather than using fossil-based carbon raw materials. Industry members see increasing support for using “bio-based” for segregated, C14-identified content but not for


www.compoundingworld.com


“mass-balanced” (sometimes called “bio-attribut- ed”) polymers which are made using processes that combine bio-based feedstocks with fossil- based feedstocks. In this method, the feedstocks are not segregated before the reactor, so the polymers do not necessarily have biocontent that can be experimentally measured via radiocarbon analysis. They can, however, be certified under programs such as ISCC Plus (see box). The US Department of Agriculture’s BioPre-


ferred Program was created by legislation in 2002 to help develop markets for bio-based products. The program specifies a minimum bio-based content (with the amount depending on the product category) to qualify for the BioPreferred program and to use its label. Currently, this bio-based content must be third-party certified using ASTM D6866. TÜV Austria’s OK Biobased Program also uses radiocarbon testing to confirm bio-based carbon


November 2024 | COMPOUNDING WORLD 13


IMAGE: SHUTTERSTOCK


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