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MATERIALS | FLAME RETARDANTS


such as Euroclass E, Bfl or UL-94 V-O at 4mm thickness (based on a loading of 20%).


Mineral opportunities Boron-based multifunctional fire retardants can function as flame retardants, smoke suppressants, afterglow suppressants and anti-tracking/anti-arc- ing agents. Borates function as flame retardants predominately in the condensed phase, with their performance able to be enhanced with the use of various co-additives. Used alone they can function as flame retardants in char-forming polymers such as polyethersulphone and polyimide. According to Kelvin Shen, a consultant for US


Borax, hexagonal boron nitride (h-BN) will play an increasingly important role in thermal management and flame retardancy in electrical and electronic applications. Commonly referred to as “white graphite” due to a plate-like hexagonal structure similar to graphite, it has been found to be a good flame retardant for many polymer systems. H-BN is an electrically insulating and highly heat conductive additive having high anisotropic thermal conductivity properties that are desired for many applications. It is stable in inert or reducing


atmospheres to about 2,700°C and in oxidising atmospheres to 850°C. Graphite itself has potential for use as a flame


retardant — expandable graphite forms a volumi- nous, thermally stable barrier residue in a fire. German company Luh is continuing research with the Institute of Polymer Technology of University Erlangen-Nuremberg aimed at providing the best possible flame-retardant effect at the lowest possible input quantity using its GHL PX 95 HT 270 product. The work is aimed at use in polyamides in particular and the company says low heat release with very low smoke production at filling rates as low as 15wt% is possible. A synergistic flame retardant system based on expandable graphite, aluminium phosphinate and melamine polyphos- phate has also been developed. With the current instability in polymer prices and availability, Europiren says it has devoted resourc- es to supporting its wire and cable clients in overcoming problems by optimising formulations and developing alternatives based on available raw materials. “Although EVA is an important compo- nent in HFFR cable formulations, it appeared possible to minimise its amount or even exclude it


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