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Table 1. Binders, Additives and Environmental Issues Present for Green Sand Cast Steel, Iron, Aluminum and Copper-Base Alloys Factors


Steel Binder


Sodium Bentonite Calcium Bentonite


Bentonite With Processed Carbon Bentonite Processed With Magnesium Fireclay


Carbon Additives


Seacoal Gilsonite


Causticized Lignite Cellulose


Cereal/Starch Polymers or Surfactants Inorganic Additives Soda Ash Advanced Oxidation Core Sand Additions


Coldbox Hotbox Shell


Sodium Silicate Other Additives


Dust Collector Fines Release Agents


Environmental Issues


Emissions (Pouring, Cooling, Shakeout) Without Cores Emissions (Pouring, Cooling, Shakeout) With Cores ) Without Cores


Greenhouse Gases (CO & CO2


Emission Characteristics as Related to the 1,800F LOI Molding Sand % >5 LOI or >1.25 Volatiles


5-3 LOI or 1.25-0.75 Volatiles


Reduction of Emissions as Related to LOI & Volatiles in Molding Sand Reduce LOI & Volatile Matter With Less Carbonaceous Additives


Change Carbon Form From Gilsonite to Causticized Lignite Change Carbon From Gilsonite to Seacoal


Change Carbon From Seacoal to Seacoal/Causticized Lignite Blend Lowest


Medium Lowest


Highest Highest Highest


Medium Highest Medium


Lowest Lowest Lowest


No Yes


Yes Yes


Yes Yes


Yes Yes


Yes n/a n/a Yes


Yes Yes Yes n/a


Yes Yes Yes n/a


Yes n/a Yes Yes


No No


Yes Yes


Yes Yes


No No


No No No No


Predominant Yes


Predominant Yes Yes Yes Yes Yes


Predominant Yes No


Yes No


Yes


No No No No


Yes Yes


Predominant Rare No


Yes No


Predominant Yes Yes Yes Yes


Yes


Predominant Yes Yes No


Yes


Predominant Yes Yes Yes


Iron Brass


Aluminum


Highest Medium Lowest


Highest Medium Lowest


Highest Medium Lowest


Highest Medium Lowest


Medium


No Reference No Reference No Reference


Highest Highest Medium Lowest


Highest Medium Medium Lowest


Medium


No Reference No Reference No Reference


Reading the Table If a factor is marked “predominant,” that binder or additive is frequently used in sand casting of that particular metal. If a


factor is marked “rare,” it is rarely used. If a binder or additive is marked “no,” it is not used in casting that metal type. If “yes,” then it is used. For the environmental factors, “lowest,” “medium” and “highest” refers to the extent an emission characteristic is present in conjunction with a metal type. The abbreviation n/a means there is no information available.


28 MODERN CASTING / October 2010


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